In
chemistry, the
standard state of a material is its
state at 1
bar (100
kilopascals exactly). This pressure was changed from 1
atm (101.325 kilopascals) by
IUPAC in 1990. The standard state of a material can be defined at any given temperature, most commonly 25 degrees
Celsius, although quite a few texts (especially in related disciplines such as physics and engineering) use 0 degrees
Celsius for
Standard Temperature and Pressure (STP).
It should be noted that the standard state is an
arbitrarily chosen non-zero value, not a natural zero point.
For a given material or
substance, the standard state is the
reference state for the material's thermodynamic state properties such as
enthalpy,
entropy,
Gibbs free energy, and for many other material standards. The
standard enthalpy of formation for an element in its standard state is 0.
When the standard state is referred to in a
chemical reaction, it also includes the condition that the
concentrations of all
solutions are at unity (or another designated quantity) for whatever measure of concentration is specified. If that's
molarity that would be 1
mol·
dm-3 and for
molality 1 mol·
kg-1. If
mole fraction is used, the pure liquid or solid is the standard state (
x=1). As it's possible (and in principle legitimate) to take a different unit for each of the species in the reaction, the nature of the standard state needs to be
specified when reporting or tabulating. Although a definition involving 1 mol/L (molarity at unity) of A in combination with pure B (mole fraction at unity) is clearly a condition that can never be met, such a non-existent standard state nevertheless leads to a consistent system of tabulated values, provided it's used consistently by all. Of course these values are
different from those where a different standard state is adopted.
In the time of their development (the 19th century) the
Plimsoll - symbol was adopted as a superscript
o to indicate the non-zero nature of the chosen reference state. For typographic reasons this symbol is often abridged to a rather misleading zero superscript
0 in later texts.
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